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Tridymite (low tridymite) SiO2, Physical and Chemical Properties

In thin section, tridymite can be distinguished by its low birefringence, low refractive index (RI), moderate relief, and typical habit often showing
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Origin of Name

From Greek for “threefold”, a reference to its habit of forming compound crystals of three individuals of threetriangular wedge-shaped crystals.

Hand Specimen Identification

Tridymite is usually sufficiently fine grained that X-ray or optical measurements are needed for identification. It is sometimes confused with zeolites.

Tridymite

Physical Properties

Hardness 6 to 7
Specific Gravity 2.28
luster/transparency vitreous/transparent to translucent
Color colourless
streak white
Fracture Conchoidal
Cleavage Absent

Optical Properties

In thin section, tridymite can be distinguished by its low birefringence, low refractive index (RI), moderate relief, and typical habit often showing wedge-shaped twins. Low tridymite: biaxial (+); alfa = 1.478, beta = 1.479, gama = 1.481, delta = 0.003, 2V = 70°.

3D Crystal Structure

Crystal structure of low-Tridymite {111}

Crystallography

Low tridymite is orthorhombic, a = 9.9, b = 17.1, c= 16.3, Z = 64; space group P222; point group 222.

Habit

Characteristic habit includes wedge-shaped crystals in vesicles or on the walls of cavities of volcanic rocks. Crystals belong to crystal class 222, but often appear as twinned pseudomorphs after high tridymite (6/m2/m2/m).

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Structure and Composition

Tridymite may contain minute amounts of Al³+ and alkalis. Its structure consists of sheets of SiO4 tetrahedra joined together by bridging oxygens. Three tridymite polymorphs are known (low, middle, and high tridymite).

Occurrence and Associations

Tridymite is found in high-temperature silicic igneous rocks, where it commonly associates with other high-temperature minerals, including sanidine and cristobalite. It is also found in some stony meteorites and lunar basalts.

Related Minerals

SiO2 polymorphs include quartz, cristobalite, tridymite, coesite, and stishovite.

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